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Photosonochemical catalytic ring opening of α-epoxyketones
The combination of ultrasound and photochemical methods has been used for the catalytic ring opening of α-epoxyketones by 1-benzyl-2,4,6-triphenylpyridinium tetrafluoroborate (NBTPT) as photocatalyst in methanol. Sonication of these compounds in the presence of NBTPT did not result in the opening of...
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Formato: | Texto |
Lenguaje: | English |
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Beilstein-Institut
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810301/ https://www.ncbi.nlm.nih.gov/pubmed/17257437 http://dx.doi.org/10.1186/1860-5397-3-2 |
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author | Memarian, Hamid R Saffar-Teluri, Ali |
author_facet | Memarian, Hamid R Saffar-Teluri, Ali |
author_sort | Memarian, Hamid R |
collection | PubMed |
description | The combination of ultrasound and photochemical methods has been used for the catalytic ring opening of α-epoxyketones by 1-benzyl-2,4,6-triphenylpyridinium tetrafluoroborate (NBTPT) as photocatalyst in methanol. Sonication of these compounds in the presence of NBTPT did not result in the opening of epoxide ring, but the use of ultrasound increased the rate of photoreaction. |
format | Text |
id | pubmed-1810301 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-18103012007-03-06 Photosonochemical catalytic ring opening of α-epoxyketones Memarian, Hamid R Saffar-Teluri, Ali Beilstein J Org Chem Full Research Paper The combination of ultrasound and photochemical methods has been used for the catalytic ring opening of α-epoxyketones by 1-benzyl-2,4,6-triphenylpyridinium tetrafluoroborate (NBTPT) as photocatalyst in methanol. Sonication of these compounds in the presence of NBTPT did not result in the opening of epoxide ring, but the use of ultrasound increased the rate of photoreaction. Beilstein-Institut 2007-01-27 /pmc/articles/PMC1810301/ /pubmed/17257437 http://dx.doi.org/10.1186/1860-5397-3-2 Text en Copyright © 2007, Memarian and Saffar-Teluri https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Memarian, Hamid R Saffar-Teluri, Ali Photosonochemical catalytic ring opening of α-epoxyketones |
title | Photosonochemical catalytic ring opening of α-epoxyketones |
title_full | Photosonochemical catalytic ring opening of α-epoxyketones |
title_fullStr | Photosonochemical catalytic ring opening of α-epoxyketones |
title_full_unstemmed | Photosonochemical catalytic ring opening of α-epoxyketones |
title_short | Photosonochemical catalytic ring opening of α-epoxyketones |
title_sort | photosonochemical catalytic ring opening of α-epoxyketones |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1810301/ https://www.ncbi.nlm.nih.gov/pubmed/17257437 http://dx.doi.org/10.1186/1860-5397-3-2 |
work_keys_str_mv | AT memarianhamidr photosonochemicalcatalyticringopeningofaepoxyketones AT saffarteluriali photosonochemicalcatalyticringopeningofaepoxyketones |