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Regioselective Synthesis of Bis(2-halo-3-pyridyl) Dichalcogenides (E = S, Se and Te): Directed Ortho-Lithiation of 2-halopyridines

A novel method for the preparation of hitherto unknown symmetrical bis(2-halo-3-pyridyl) dichalcogenides (E = S, Se and Te) by the oxidation of intermediate 2-halo-3-pyridyl chalcogenolate, prepared by lithiation of 2-halo pyridines using lithium diisopropylamine is being reported. All the newly syn...

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Detalles Bibliográficos
Autores principales: Bhasin, K. K., Singh, Neelam, Doomra, Shivani, Arora, Ekta, Ram, Ganga, Singh, Sukhjinder, Nagpal, Yogesh, Mehta, S. K., Klapotke, T. M.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1885866/
https://www.ncbi.nlm.nih.gov/pubmed/17611613
http://dx.doi.org/10.1155/2007/69263