Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy

Addition of low order phenyldimethylsilylcyanocuprates to allenes followed by "in situ" reaction of the intermediate silylcuprate with electrophiles ("the silylcuprate strategy") provides new routes for the synthesis of functionalised allylsilanes, which undergo highly stereocont...

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Detalles Bibliográficos
Autores principales: Barbero, Asunción, Pulido, Francisco J, Sañudo, M Carmen
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1894809/
https://www.ncbi.nlm.nih.gov/pubmed/17519004
http://dx.doi.org/10.1186/1860-5397-3-16
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author Barbero, Asunción
Pulido, Francisco J
Sañudo, M Carmen
author_facet Barbero, Asunción
Pulido, Francisco J
Sañudo, M Carmen
author_sort Barbero, Asunción
collection PubMed
description Addition of low order phenyldimethylsilylcyanocuprates to allenes followed by "in situ" reaction of the intermediate silylcuprate with electrophiles ("the silylcuprate strategy") provides new routes for the synthesis of functionalised allylsilanes, which undergo highly stereocontrolled silicon-assisted intramolecular cyclizations leading to three to seven membered ring-formation.
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spelling pubmed-18948092007-06-20 Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy Barbero, Asunción Pulido, Francisco J Sañudo, M Carmen Beilstein J Org Chem Review Addition of low order phenyldimethylsilylcyanocuprates to allenes followed by "in situ" reaction of the intermediate silylcuprate with electrophiles ("the silylcuprate strategy") provides new routes for the synthesis of functionalised allylsilanes, which undergo highly stereocontrolled silicon-assisted intramolecular cyclizations leading to three to seven membered ring-formation. Beilstein-Institut 2007-05-22 /pmc/articles/PMC1894809/ /pubmed/17519004 http://dx.doi.org/10.1186/1860-5397-3-16 Text en Copyright © 2007, Barbero et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Barbero, Asunción
Pulido, Francisco J
Sañudo, M Carmen
Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title_full Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title_fullStr Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title_full_unstemmed Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title_short Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
title_sort allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1894809/
https://www.ncbi.nlm.nih.gov/pubmed/17519004
http://dx.doi.org/10.1186/1860-5397-3-16
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AT pulidofranciscoj allylsilanesinthesynthesisofthreetosevenmemberedringsthesilylcupratestrategy
AT sanudomcarmen allylsilanesinthesynthesisofthreetosevenmemberedringsthesilylcupratestrategy

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