m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations

m-Iodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, c...

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Detalles Bibliográficos
Autores principales: Kirschning, Andreas, Yusubov, Mekhman S, Yusubova, Roza Y, Chi, Ki-Whan, Park, Joo Y
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1924527/
https://www.ncbi.nlm.nih.gov/pubmed/17543133
http://dx.doi.org/10.1186/1860-5397-3-19
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author Kirschning, Andreas
Yusubov, Mekhman S
Yusubova, Roza Y
Chi, Ki-Whan
Park, Joo Y
author_facet Kirschning, Andreas
Yusubov, Mekhman S
Yusubova, Roza Y
Chi, Ki-Whan
Park, Joo Y
author_sort Kirschning, Andreas
collection PubMed
description m-Iodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl.
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spelling pubmed-19245272007-07-18 m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations Kirschning, Andreas Yusubov, Mekhman S Yusubova, Roza Y Chi, Ki-Whan Park, Joo Y Beilstein J Org Chem Full Research Paper m-Iodosylbenzoic acid performs iodinations of arenes in the presence of iodine at room temperature in acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form). The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion exchange resin or from the basic aqueous solution by simple acidification with HCl. Beilstein-Institut 2007-06-04 /pmc/articles/PMC1924527/ /pubmed/17543133 http://dx.doi.org/10.1186/1860-5397-3-19 Text en Copyright © 2007, Kirschning et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kirschning, Andreas
Yusubov, Mekhman S
Yusubova, Roza Y
Chi, Ki-Whan
Park, Joo Y
m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title_full m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title_fullStr m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title_full_unstemmed m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title_short m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
title_sort m-iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1924527/
https://www.ncbi.nlm.nih.gov/pubmed/17543133
http://dx.doi.org/10.1186/1860-5397-3-19
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