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Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate

The coordination chemistry of the 2-His-1-carboxylate facial triad mimics 3,3-bis(1-methylimidazol-2-yl)propionate (MIm(2)Pr) and 3,3-bis(1-ethyl-4-isopropylimidazol-2-yl) propionate (iPrEtIm(2)Pr) towards ZnCl(2) was studied both in solution and in the solid state. Different coordination modes were...

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Detalles Bibliográficos
Autores principales: Bruijnincx, Pieter C. A., Lutz, Martin, den Breejen, Johan P., Spek, Anthony L., van Koten, Gerard, Klein Gebbink, Robertus J. M.
Formato: Texto
Lenguaje:English
Publicado: Springer-Verlag 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2039866/
https://www.ncbi.nlm.nih.gov/pubmed/17828423
http://dx.doi.org/10.1007/s00775-007-0285-z