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Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides
We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene α-D-glucopyranoside in high yields and which does not require the use of catalysts.
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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Beilstein-Institut
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2048501/ https://www.ncbi.nlm.nih.gov/pubmed/17897436 http://dx.doi.org/10.1186/1860-5397-3-26 |
| _version_ | 1782137152886276096 |
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| author | Ness, Kerry Ann Migaud, Marie E |
| author_facet | Ness, Kerry Ann Migaud, Marie E |
| author_sort | Ness, Kerry Ann |
| collection | PubMed |
| description | We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene α-D-glucopyranoside in high yields and which does not require the use of catalysts. |
| format | Text |
| id | pubmed-2048501 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-20485012007-11-01 Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides Ness, Kerry Ann Migaud, Marie E Beilstein J Org Chem Full Research Paper We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene α-D-glucopyranoside in high yields and which does not require the use of catalysts. Beilstein-Institut 2007-09-26 /pmc/articles/PMC2048501/ /pubmed/17897436 http://dx.doi.org/10.1186/1860-5397-3-26 Text en Copyright © 2007, Ness and Migaud https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Ness, Kerry Ann Migaud, Marie E Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title | Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title_full | Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title_fullStr | Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title_full_unstemmed | Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title_short | Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| title_sort | solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2048501/ https://www.ncbi.nlm.nih.gov/pubmed/17897436 http://dx.doi.org/10.1186/1860-5397-3-26 |
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