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The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines
BACKGROUND: Chiral base desymmetrisation of dimethyl sulfoximines could provide a general route to chiral, enantioenriched dialkyl sulfoximines with potential for use in asymmetric catalysis. RESULTS: Asymmetric deprotonation of N-trialkylsilyl dimethyl sulfoximines with either enantiomer of lithium...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2100055/ https://www.ncbi.nlm.nih.gov/pubmed/17939868 http://dx.doi.org/10.1186/1860-5397-3-33 |