THE APPLICATION OF QUANTUM MECHANICS TO CERTAIN CASES OF HOMOGENEOUS CATALYSIS. I

1. The activation energy for the hydrolytic breaking of a peptid linkage has been calculated from quantum mechanical considerations. 2. The relative catalytic effects of H(+) and OH(-) and the mechanism of these effects have been calculated and discussed. 3. These effects are both qualitatively and...

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Detalles Bibliográficos
Autor principal: Stearn, Allen E.
Formato: Texto
Lenguaje:English
Publicado: The Rockefeller University Press 1934
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2141347/
https://www.ncbi.nlm.nih.gov/pubmed/19872832
Descripción
Sumario:1. The activation energy for the hydrolytic breaking of a peptid linkage has been calculated from quantum mechanical considerations. 2. The relative catalytic effects of H(+) and OH(-) and the mechanism of these effects have been calculated and discussed. 3. These effects are both qualitatively and semiquantitatively in agreement with experiment.

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