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Catalysis over zinc-incorporated berlinite (ZnAlPO(4)) of the methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to form dimethylhexane-1,6-dicarbamate

BACKGROUND: The alkoxycarbonylation of diamines with dialkyl carbonates presents promising route for the synthesis of dicarbamates, one that is potentially 'greener' owing to the lack of a reliance on phosgene. While a few homogeneous catalysts have been reported, no heterogeneous catalyst...

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Detalles Bibliográficos
Autores principales: Sun, Da-Lei, Deng, Jian-Ru, Chao, Zi-Sheng
Formato: Texto
Lenguaje:English
Publicado: BioMed Central 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2211281/
https://www.ncbi.nlm.nih.gov/pubmed/17988376
http://dx.doi.org/10.1186/1752-153X-1-27