Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.

Detalles Bibliográficos
Autores principales: Allais, Florent, Boivin, Jean, Nguyen, Van Tai
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2007
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2213662/
https://www.ncbi.nlm.nih.gov/pubmed/18076755
http://dx.doi.org/10.1186/1860-5397-3-46
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author Allais, Florent
Boivin, Jean
Nguyen, Van Tai
author_facet Allais, Florent
Boivin, Jean
Nguyen, Van Tai
author_sort Allais, Florent
collection PubMed
description Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route.
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spelling pubmed-22136622008-01-25 Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air Allais, Florent Boivin, Jean Nguyen, Van Tai Beilstein J Org Chem Full Research Paper Experiments conducted with deuterated compounds demonstrated that during the reduction of S-alkylxanthates with triethylborane, the hydrogen atom transferred has several competing origins. Hydrogen abstraction from water (or an alcohol) is the most favourable route. Beilstein-Institut 2007-12-12 /pmc/articles/PMC2213662/ /pubmed/18076755 http://dx.doi.org/10.1186/1860-5397-3-46 Text en Copyright © 2007, Allais et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Allais, Florent
Boivin, Jean
Nguyen, Van Tai
Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_full Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_fullStr Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_full_unstemmed Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_short Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air
title_sort part 2. mechanistic aspects of the reduction of s-alkyl-thionocarbonates in the presence of triethylborane and air
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2213662/
https://www.ncbi.nlm.nih.gov/pubmed/18076755
http://dx.doi.org/10.1186/1860-5397-3-46
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AT nguyenvantai part2mechanisticaspectsofthereductionofsalkylthionocarbonatesinthepresenceoftriethylboraneandair

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