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THE VALIDITY OF THE GLASS ELECTRODE IN AMMONIUM CHLORIDE BUFFERS

It is shown that the glass electrode may be used without appreciable error to measure pH of ammonia or ammonium chloride buffers, but that corrections must be applied above pH 8.6 if sodium ions are present in the unknown solution. Corrections are given for values from pH 8.6 to 9.4. A slight furthe...

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Detalles Bibliográficos
Autor principal: Hill, Samuel E.
Formato: Texto
Lenguaje:English
Publicado: The Rockefeller University Press 1929
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2323745/
https://www.ncbi.nlm.nih.gov/pubmed/19872499
Descripción
Sumario:It is shown that the glass electrode may be used without appreciable error to measure pH of ammonia or ammonium chloride buffers, but that corrections must be applied above pH 8.6 if sodium ions are present in the unknown solution. Corrections are given for values from pH 8.6 to 9.4. A slight further modification of form of glass electrode used by previous workers is described.