Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes

Three isomeric Me(8)[14]anes, L(A), L(B) and L(C), undergo complexation with copper(II) salts to form a series of [CuLX(n)(H(2)O)(x)]X(y).(H(2)O)(z) complexes where L = L(A), L(B) and L(C); X = Cl, Br, NO(3); n, x, y and z may have values of 0, 1 or 2. The complexes have been characterised on the ba...

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Autores principales: Hazari, Saroj K. S., Roy, Tapashi G., Dey, Benu K., Das, Suvash C., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 1997
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2365080/
https://www.ncbi.nlm.nih.gov/pubmed/18475797
http://dx.doi.org/10.1155/MBD.1997.255
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author Hazari, Saroj K. S.
Roy, Tapashi G.
Dey, Benu K.
Das, Suvash C.
Tiekink, Edward R. T.
author_facet Hazari, Saroj K. S.
Roy, Tapashi G.
Dey, Benu K.
Das, Suvash C.
Tiekink, Edward R. T.
author_sort Hazari, Saroj K. S.
collection PubMed
description Three isomeric Me(8)[14]anes, L(A), L(B) and L(C), undergo complexation with copper(II) salts to form a series of [CuLX(n)(H(2)O)(x)]X(y).(H(2)O)(z) complexes where L = L(A), L(B) and L(C); X = Cl, Br, NO(3); n, x, y and z may have values of 0, 1 or 2. The complexes have been characterised on the basis of analytical, spectroscopic, magnetic and conductance data. Further, the X-ray crystal structure of one complex, [CuL(B)(OH(2))(2)](NO(3))(2), has been determined. The antifungal activity of all three isomeric ligands and their complexes has been investigated against a range of phytopathogenic fungi.
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spelling pubmed-23650802008-05-12 Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes Hazari, Saroj K. S. Roy, Tapashi G. Dey, Benu K. Das, Suvash C. Tiekink, Edward R. T. Met Based Drugs Research Article Three isomeric Me(8)[14]anes, L(A), L(B) and L(C), undergo complexation with copper(II) salts to form a series of [CuLX(n)(H(2)O)(x)]X(y).(H(2)O)(z) complexes where L = L(A), L(B) and L(C); X = Cl, Br, NO(3); n, x, y and z may have values of 0, 1 or 2. The complexes have been characterised on the basis of analytical, spectroscopic, magnetic and conductance data. Further, the X-ray crystal structure of one complex, [CuL(B)(OH(2))(2)](NO(3))(2), has been determined. The antifungal activity of all three isomeric ligands and their complexes has been investigated against a range of phytopathogenic fungi. Hindawi Publishing Corporation 1997 /pmc/articles/PMC2365080/ /pubmed/18475797 http://dx.doi.org/10.1155/MBD.1997.255 Text en Copyright © 1997 Hindawi Publishing Corporation. http://creativecommons.org/licenses/by/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Hazari, Saroj K. S.
Roy, Tapashi G.
Dey, Benu K.
Das, Suvash C.
Tiekink, Edward R. T.
Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title_full Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title_fullStr Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title_full_unstemmed Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title_short Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes
title_sort synthesis, characterisation and antifungal activities of some new copper(ii) complexes of isomeric 3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecanes
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2365080/
https://www.ncbi.nlm.nih.gov/pubmed/18475797
http://dx.doi.org/10.1155/MBD.1997.255
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