Synthesis and Biological Activity of Organothiophosphoryl Polyoxotungstates

Organothiophosphoryl polyoxotungstates R(∋)XW(∞∞)O(∋∃)(/-) , R(∋) P(∋)W(∞),O(∞)(/-), R(∋)PW(∃)O(∋) (Δ)(-)(X = P, Si, Ge, B or Ga; R = PhP(S), C(6)H(11)P(S)) have been prepared from lacunary polyoxoanions and PhP(S). The products were characterized by elemental analysis, IR, and NMR spectroscopy. Acc...

Descripción completa

Detalles Bibliográficos
Autores principales: Sun, Zhengang, Liu, Jutao, Ma, Jianfang, Liu, Jingfu
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2002
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2365281/
https://www.ncbi.nlm.nih.gov/pubmed/18476003
http://dx.doi.org/10.1155/MBD.2002.257
Descripción
Sumario:Organothiophosphoryl polyoxotungstates R(∋)XW(∞∞)O(∋∃)(/-) , R(∋) P(∋)W(∞),O(∞)(/-), R(∋)PW(∃)O(∋) (Δ)(-)(X = P, Si, Ge, B or Ga; R = PhP(S), C(6)H(11)P(S)) have been prepared from lacunary polyoxoanions and PhP(S). The products were characterized by elemental analysis, IR, and NMR spectroscopy. According to spectroscopic observations, the hybrid anions consist of a lacunary anion framework on which are grafted two equivalent or groups through P-O-W bridges. Some of the title compounds showed the antigerm activity.

Ejemplares similares