Pt(II) and Pd(II) Complexes with β-Alanine

A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the (195)Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alan...

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Detalles Bibliográficos
Autores principales: Krylova, L. F., Kovtunova, L. M., Romanenko, G. V.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2008
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2408677/
https://www.ncbi.nlm.nih.gov/pubmed/18528519
http://dx.doi.org/10.1155/2008/983725
Descripción
Sumario:A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the (195)Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alanine as well as of the halide complexes of trans-[M(β-AlaH)(2)Cl(2)] (M = Pt, Pd) and trans-K(2)[Pt(β-Ala)(2)I(2)] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of (195)Pt,(13)C,(1)H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds.

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