Pt(II) and Pd(II) Complexes with β-Alanine

A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the (195)Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alan...

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Autores principales: Krylova, L. F., Kovtunova, L. M., Romanenko, G. V.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2008
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2408677/
https://www.ncbi.nlm.nih.gov/pubmed/18528519
http://dx.doi.org/10.1155/2008/983725
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author Krylova, L. F.
Kovtunova, L. M.
Romanenko, G. V.
author_facet Krylova, L. F.
Kovtunova, L. M.
Romanenko, G. V.
author_sort Krylova, L. F.
collection PubMed
description A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the (195)Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alanine as well as of the halide complexes of trans-[M(β-AlaH)(2)Cl(2)] (M = Pt, Pd) and trans-K(2)[Pt(β-Ala)(2)I(2)] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of (195)Pt,(13)C,(1)H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds.
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spelling pubmed-24086772008-06-04 Pt(II) and Pd(II) Complexes with β-Alanine Krylova, L. F. Kovtunova, L. M. Romanenko, G. V. Bioinorg Chem Appl Research Article A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the (195)Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with β-alanine as well as of the halide complexes of trans-[M(β-AlaH)(2)Cl(2)] (M = Pt, Pd) and trans-K(2)[Pt(β-Ala)(2)I(2)] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of (195)Pt,(13)C,(1)H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds. Hindawi Publishing Corporation 2008 2008-05-26 /pmc/articles/PMC2408677/ /pubmed/18528519 http://dx.doi.org/10.1155/2008/983725 Text en Copyright © 2008 L. F. Krylova et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Krylova, L. F.
Kovtunova, L. M.
Romanenko, G. V.
Pt(II) and Pd(II) Complexes with β-Alanine
title Pt(II) and Pd(II) Complexes with β-Alanine
title_full Pt(II) and Pd(II) Complexes with β-Alanine
title_fullStr Pt(II) and Pd(II) Complexes with β-Alanine
title_full_unstemmed Pt(II) and Pd(II) Complexes with β-Alanine
title_short Pt(II) and Pd(II) Complexes with β-Alanine
title_sort pt(ii) and pd(ii) complexes with β-alanine
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2408677/
https://www.ncbi.nlm.nih.gov/pubmed/18528519
http://dx.doi.org/10.1155/2008/983725
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