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Valence isomerization of 2-phospha-4-silabicyclo[1.1.0]butane: a high-level ab initio study
The rearrangements for 2-phospha-4-silabicyclo[1.1.0]butane, analogous to the valence isomerization of the hydrocarbons bicyclobutane, 1,3-butadiene, and cyclobutene, were studied at the (U)QCISD(T)/6-311+G**//(U)QCISD/6-31G* level of theory. The monocyclic 1,2-dihydro-1,2-phosphasiletes are shown t...
Autores principales: | Slootweg, J. Chris, Ehlers, Andreas W., Lammertsma, Koop |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Springer-Verlag
2006
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2441497/ https://www.ncbi.nlm.nih.gov/pubmed/16642334 http://dx.doi.org/10.1007/s00894-005-0041-7 |
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