Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester

Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields.

Detalles Bibliográficos
Autores principales: Liu, Guo-Bin, Zhao, Hong-Yun
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2511026/
https://www.ncbi.nlm.nih.gov/pubmed/18941497
http://dx.doi.org/10.3762/bjoc.4.27
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author Liu, Guo-Bin
Zhao, Hong-Yun
author_facet Liu, Guo-Bin
Zhao, Hong-Yun
author_sort Liu, Guo-Bin
collection PubMed
description Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields.
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spelling pubmed-25110262008-10-20 Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester Liu, Guo-Bin Zhao, Hong-Yun Beilstein J Org Chem Preliminary Communication Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields. Beilstein-Institut 2008-07-30 /pmc/articles/PMC2511026/ /pubmed/18941497 http://dx.doi.org/10.3762/bjoc.4.27 Text en Copyright © 2008, Liu and Zhao https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Preliminary Communication
Liu, Guo-Bin
Zhao, Hong-Yun
Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title_full Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title_fullStr Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title_full_unstemmed Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title_short Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
title_sort ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
topic Preliminary Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2511026/
https://www.ncbi.nlm.nih.gov/pubmed/18941497
http://dx.doi.org/10.3762/bjoc.4.27
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AT zhaohongyun rucatalyzeddehydrogenativecouplingofcarboxylicacidsandsilanesanewmethodforthepreparationofsilylester

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