Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT

Novel [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) analogues containing benzo[b]thiophene (3a, 3b) and thieno[3,2-b]thiophene (3c, 3d) were synthesized and characterized. The morphology of the thin films prepared from the mixtures of these methanofullerenes with regioregular poly(3-hexylthiophe...

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Autores principales: Matsumoto, Fukashi, Moriwaki, Kazuyuki, Takao, Yuko, Ohno, Toshinobu
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2568877/
https://www.ncbi.nlm.nih.gov/pubmed/18941618
http://dx.doi.org/10.3762/bjoc.4.33
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author Matsumoto, Fukashi
Moriwaki, Kazuyuki
Takao, Yuko
Ohno, Toshinobu
author_facet Matsumoto, Fukashi
Moriwaki, Kazuyuki
Takao, Yuko
Ohno, Toshinobu
author_sort Matsumoto, Fukashi
collection PubMed
description Novel [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) analogues containing benzo[b]thiophene (3a, 3b) and thieno[3,2-b]thiophene (3c, 3d) were synthesized and characterized. The morphology of the thin films prepared from the mixtures of these methanofullerenes with regioregular poly(3-hexylthiophene) (P3HT) was investigated by AFM measurement and UV-Vis absorption spectroscopy. A solubility test of these methanofullerenes was performed by using dichloromethane as a solvent. es-TThCBM (3d) exhibited 1.4 times greater solubility in dichloromethane than PCBM.
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spelling pubmed-25688772008-10-20 Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT Matsumoto, Fukashi Moriwaki, Kazuyuki Takao, Yuko Ohno, Toshinobu Beilstein J Org Chem Full Research Paper Novel [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) analogues containing benzo[b]thiophene (3a, 3b) and thieno[3,2-b]thiophene (3c, 3d) were synthesized and characterized. The morphology of the thin films prepared from the mixtures of these methanofullerenes with regioregular poly(3-hexylthiophene) (P3HT) was investigated by AFM measurement and UV-Vis absorption spectroscopy. A solubility test of these methanofullerenes was performed by using dichloromethane as a solvent. es-TThCBM (3d) exhibited 1.4 times greater solubility in dichloromethane than PCBM. Beilstein-Institut 2008-09-29 /pmc/articles/PMC2568877/ /pubmed/18941618 http://dx.doi.org/10.3762/bjoc.4.33 Text en Copyright © 2008, Matsumoto et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Matsumoto, Fukashi
Moriwaki, Kazuyuki
Takao, Yuko
Ohno, Toshinobu
Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title_full Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title_fullStr Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title_full_unstemmed Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title_short Synthesis of thienyl analogues of PCBM and investigation of morphology of mixtures in P3HT
title_sort synthesis of thienyl analogues of pcbm and investigation of morphology of mixtures in p3ht
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2568877/
https://www.ncbi.nlm.nih.gov/pubmed/18941618
http://dx.doi.org/10.3762/bjoc.4.33
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