Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds

Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other appl...

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Autores principales: Osipov, Maksim, Chu, Qianli, Geib, Steven J, Curran, Dennis P, Weber, Stephen G
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2587948/
https://www.ncbi.nlm.nih.gov/pubmed/19043477
http://dx.doi.org/10.3762/bjoc.4.36
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author Osipov, Maksim
Chu, Qianli
Geib, Steven J
Curran, Dennis P
Weber, Stephen G
author_facet Osipov, Maksim
Chu, Qianli
Geib, Steven J
Curran, Dennis P
Weber, Stephen G
author_sort Osipov, Maksim
collection PubMed
description Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other applications.
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spelling pubmed-25879482008-11-28 Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds Osipov, Maksim Chu, Qianli Geib, Steven J Curran, Dennis P Weber, Stephen G Beilstein J Org Chem Full Research Paper Several lower-rim perfluoroalkylated (fluorous) calix[4]arenes have been synthesized by O-alkylation of the parent calix[4]arene. The compounds are formed in the cone conformation. They are soluble in several fluorous solvents and show promise for use in sensing, selective extractions and other applications. Beilstein-Institut 2008-10-20 /pmc/articles/PMC2587948/ /pubmed/19043477 http://dx.doi.org/10.3762/bjoc.4.36 Text en Copyright © 2008, Osipov et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Osipov, Maksim
Chu, Qianli
Geib, Steven J
Curran, Dennis P
Weber, Stephen G
Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title_full Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title_fullStr Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title_full_unstemmed Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title_short Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
title_sort synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2587948/
https://www.ncbi.nlm.nih.gov/pubmed/19043477
http://dx.doi.org/10.3762/bjoc.4.36
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