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1,5-Asymmetric induction during nucleophilic additions to arene­tricarbonyl­chromium complexes: tri­carbonyl­(η(6)-1-methyl-4-{spiro­[(1R,2S)-1,7,7-trimethyl­bicyclo­[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yl­oxy}benzene)­chromium

The tricarbonyl­chromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Detalles Bibliográficos
Autores principales: Paramahamsan, Harinandini, Pearson, Anthony J., Pinkerton, Nathalie M., Pinkerton, A. Alan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2631130/
https://www.ncbi.nlm.nih.gov/pubmed/18391373
http://dx.doi.org/10.1107/S0108270108004666
Descripción
Sumario:The tricarbonyl­chromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.