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1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium
The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2631130/ https://www.ncbi.nlm.nih.gov/pubmed/18391373 http://dx.doi.org/10.1107/S0108270108004666 |
| _version_ | 1782163909553160192 |
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| author | Paramahamsan, Harinandini Pearson, Anthony J. Pinkerton, Nathalie M. Pinkerton, A. Alan |
| author_facet | Paramahamsan, Harinandini Pearson, Anthony J. Pinkerton, Nathalie M. Pinkerton, A. Alan |
| author_sort | Paramahamsan, Harinandini |
| collection | PubMed |
| description | The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack. |
| format | Text |
| id | pubmed-2631130 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-26311302009-03-05 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium Paramahamsan, Harinandini Pearson, Anthony J. Pinkerton, Nathalie M. Pinkerton, A. Alan Acta Crystallogr C Metal-Organic Compounds The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack. International Union of Crystallography 2008-04-15 2008-03-08 /pmc/articles/PMC2631130/ /pubmed/18391373 http://dx.doi.org/10.1107/S0108270108004666 Text en © International Union of Crystallography 2008 |
| spellingShingle | Metal-Organic Compounds Paramahamsan, Harinandini Pearson, Anthony J. Pinkerton, Nathalie M. Pinkerton, A. Alan 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title | 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title_full | 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title_fullStr | 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title_full_unstemmed | 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title_short | 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| title_sort | 1,5-asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1r,2s)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium |
| topic | Metal-Organic Compounds |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2631130/ https://www.ncbi.nlm.nih.gov/pubmed/18391373 http://dx.doi.org/10.1107/S0108270108004666 |
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