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1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(η(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2′-1,3-dioxolan]-2-yloxy}benzene)chromium

The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Detalles Bibliográficos
Autores principales:	Paramahamsan, Harinandini, Pearson, Anthony J., Pinkerton, Nathalie M., Pinkerton, A. Alan
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Metal-Organic Compounds
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2631130/ https://www.ncbi.nlm.nih.gov/pubmed/18391373 http://dx.doi.org/10.1107/S0108270108004666

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