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Highly brominated anthracenes as precursors for the convenient synthesis of 2,9,10-trisubstituted anthracene derivatives

When 9,10-dibromoanthracene was treated with bromine in CCl(4) without a catalyst, 1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydroanthracene (3) was obtained in 95% yield in the absence of other stereoisomers or rearomatization products. We investigated the base-induced elimination reaction of hexabromide...

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Detalles Bibliográficos
Autores principales: Cakmak, Osman, Aydogan, Leyla, Berkil, Kiymet, Gulcin, Ilhami, Buyukgungor, Orhan
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2633663/
https://www.ncbi.nlm.nih.gov/pubmed/19190741
http://dx.doi.org/10.3762/bjoc.4.50