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Chemoselective reduction of aldehydes by ruthenium trichloride and resin-bound formates
A simple, chemoselective transfer hydrogenation of aryl aldehydes with the aid of Amberlite(®) resin formate (ARF), a stable H-donor, in the presence of catalytic ruthenium trichloride is described. Aromatic aldehydes and 1,2-diketones are reduced efficiently and selectively, while aryl ketones rema...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2633666/ https://www.ncbi.nlm.nih.gov/pubmed/19190744 http://dx.doi.org/10.3762/bjoc.4.53 |