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Closing in on Chemical Bonds by Opening up Relativity Theory
This paper develops a connection between the phenomenology of chemical bonding and the theory of relativity. Empirical correlations between electron numbers in atoms and chemical bond stabilities in molecules are first reviewed and extended. Quantitative chemical bond strengths are then related to i...
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Formato: | Texto |
Lenguaje: | English |
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Molecular Diversity Preservation International (MDPI)
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2635676/ https://www.ncbi.nlm.nih.gov/pubmed/19325749 |
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author | Whitney, Cynthia Kolb |
author_facet | Whitney, Cynthia Kolb |
author_sort | Whitney, Cynthia Kolb |
collection | PubMed |
description | This paper develops a connection between the phenomenology of chemical bonding and the theory of relativity. Empirical correlations between electron numbers in atoms and chemical bond stabilities in molecules are first reviewed and extended. Quantitative chemical bond strengths are then related to ionization potentials in elements. Striking patterns in ionization potentials are revealed when the data are viewed in an element-independent way, where element-specific details are removed via an appropriate scaling law. The scale factor involved is not explained by quantum mechanics; it is revealed only when one goes back further, to the development of Einstein’s special relativity theory. |
format | Text |
id | pubmed-2635676 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | Molecular Diversity Preservation International (MDPI) |
record_format | MEDLINE/PubMed |
spelling | pubmed-26356762009-03-25 Closing in on Chemical Bonds by Opening up Relativity Theory Whitney, Cynthia Kolb Int J Mol Sci Full Research Paper This paper develops a connection between the phenomenology of chemical bonding and the theory of relativity. Empirical correlations between electron numbers in atoms and chemical bond stabilities in molecules are first reviewed and extended. Quantitative chemical bond strengths are then related to ionization potentials in elements. Striking patterns in ionization potentials are revealed when the data are viewed in an element-independent way, where element-specific details are removed via an appropriate scaling law. The scale factor involved is not explained by quantum mechanics; it is revealed only when one goes back further, to the development of Einstein’s special relativity theory. Molecular Diversity Preservation International (MDPI) 2008-03-12 /pmc/articles/PMC2635676/ /pubmed/19325749 Text en © 2008 by MDPI |
spellingShingle | Full Research Paper Whitney, Cynthia Kolb Closing in on Chemical Bonds by Opening up Relativity Theory |
title | Closing in on Chemical Bonds by Opening up Relativity Theory |
title_full | Closing in on Chemical Bonds by Opening up Relativity Theory |
title_fullStr | Closing in on Chemical Bonds by Opening up Relativity Theory |
title_full_unstemmed | Closing in on Chemical Bonds by Opening up Relativity Theory |
title_short | Closing in on Chemical Bonds by Opening up Relativity Theory |
title_sort | closing in on chemical bonds by opening up relativity theory |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2635676/ https://www.ncbi.nlm.nih.gov/pubmed/19325749 |
work_keys_str_mv | AT whitneycynthiakolb closinginonchemicalbondsbyopeninguprelativitytheory |