The first direct synthesis of β-unsubstituted meso-decamethylcalix[5]pyrrole

The first direct synthesis of β-unsubstituted meso-decamethylcalix[5]pyrrole from pyrrole and acetone, with moderate yield, is described. The results showed that a bismuth salt was necessary to obtain calix[5]pyrrole, with the best results obtained using Bi(NO(3))(3).

Detalles Bibliográficos
Autores principales: Chacón-García, Luis, Chávez, Lizbeth, Cacho, Denisse R, Altamirano-Hernández, Josue
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2649437/
https://www.ncbi.nlm.nih.gov/pubmed/19259338
http://dx.doi.org/10.3762/bjoc.5.2
Descripción
Sumario:The first direct synthesis of β-unsubstituted meso-decamethylcalix[5]pyrrole from pyrrole and acetone, with moderate yield, is described. The results showed that a bismuth salt was necessary to obtain calix[5]pyrrole, with the best results obtained using Bi(NO(3))(3).

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