Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone

Tetraketone and tetraaldehyde derivatives 2a–d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, (1)H-NMR, (13)C-NMR and MS analysis. The crystal structure of the t...

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Autores principales: Er, Mustafa, Ustabaş, Reşat, Çoruh, Ufuk, Sancak, Kemal, Vázquez-López, Ezequiel
Formato: Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2008
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2658780/
https://www.ncbi.nlm.nih.gov/pubmed/19325842
http://dx.doi.org/10.3390/ijms9061000
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author Er, Mustafa
Ustabaş, Reşat
Çoruh, Ufuk
Sancak, Kemal
Vázquez-López, Ezequiel
author_facet Er, Mustafa
Ustabaş, Reşat
Çoruh, Ufuk
Sancak, Kemal
Vázquez-López, Ezequiel
author_sort Er, Mustafa
collection PubMed
description Tetraketone and tetraaldehyde derivatives 2a–d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, (1)H-NMR, (13)C-NMR and MS analysis. The crystal structure of the title compound 2a, C(38)H(36)O(8), is reported. Its crystal data are: monoclinic, space group P 2(1)/n with cell dimensions of a=9.0395(12) Å, b=12.6114(17) Å, c=13.8166(18) Å, β=95.875(3), V=1566.8(4) Å(3), F.W.=620.67, ρ(calc)=1.316 gcm(3) for Z=2, μ=0.092 mm(−1)
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spelling pubmed-26587802009-03-25 Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone Er, Mustafa Ustabaş, Reşat Çoruh, Ufuk Sancak, Kemal Vázquez-López, Ezequiel Int J Mol Sci Article Tetraketone and tetraaldehyde derivatives 2a–d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, (1)H-NMR, (13)C-NMR and MS analysis. The crystal structure of the title compound 2a, C(38)H(36)O(8), is reported. Its crystal data are: monoclinic, space group P 2(1)/n with cell dimensions of a=9.0395(12) Å, b=12.6114(17) Å, c=13.8166(18) Å, β=95.875(3), V=1566.8(4) Å(3), F.W.=620.67, ρ(calc)=1.316 gcm(3) for Z=2, μ=0.092 mm(−1) Molecular Diversity Preservation International (MDPI) 2008-06-13 /pmc/articles/PMC2658780/ /pubmed/19325842 http://dx.doi.org/10.3390/ijms9061000 Text en
spellingShingle Article
Er, Mustafa
Ustabaş, Reşat
Çoruh, Ufuk
Sancak, Kemal
Vázquez-López, Ezequiel
Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title_full Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title_fullStr Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title_full_unstemmed Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title_short Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
title_sort synthesis and characterization of some new tetraaldehyde and tetraketone derivatives and x-ray structure of 1,1′-(4,4′-(2-(1,3-bis(4-acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2658780/
https://www.ncbi.nlm.nih.gov/pubmed/19325842
http://dx.doi.org/10.3390/ijms9061000
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