Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry

Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol est...

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Detalles Bibliográficos
Autores principales: Kulhánek, Jiří, Bureš, Filip, Ludwig, Miroslav
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2686302/
https://www.ncbi.nlm.nih.gov/pubmed/19478966
http://dx.doi.org/10.3762/bjoc.5.11
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author Kulhánek, Jiří
Bureš, Filip
Ludwig, Miroslav
author_facet Kulhánek, Jiří
Bureš, Filip
Ludwig, Miroslav
author_sort Kulhánek, Jiří
collection PubMed
description Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions.
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spelling pubmed-26863022009-05-28 Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry Kulhánek, Jiří Bureš, Filip Ludwig, Miroslav Beilstein J Org Chem Full Research Paper Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki–Miyaura or Sonogashira coupling reactions. Beilstein-Institut 2009-04-14 /pmc/articles/PMC2686302/ /pubmed/19478966 http://dx.doi.org/10.3762/bjoc.5.11 Text en Copyright © 2009, Kulhánek et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kulhánek, Jiří
Bureš, Filip
Ludwig, Miroslav
Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_full Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_fullStr Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_full_unstemmed Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_short Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
title_sort convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2686302/
https://www.ncbi.nlm.nih.gov/pubmed/19478966
http://dx.doi.org/10.3762/bjoc.5.11
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AT buresfilip convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry
AT ludwigmiroslav convenientmethodsforpreparingpconjugatedlinkersasbuildingblocksformodularchemistry

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