Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C

The automated procedure for the monitoring of the adsorption process in the solute-sorbent-solvent system has been elaborated. It uses commercially available instrument CRYSTAF model 200. The application of CRYSTAF enabled monitoring of adsorption of linear polyethylene with weight average molar mas...

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Detalles Bibliográficos
Autores principales: Macko, Tibor, Brüll, Robert, Brinkmann, Christoph, Pasch, Harald
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2009
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2730561/
https://www.ncbi.nlm.nih.gov/pubmed/19707534
http://dx.doi.org/10.1155/2009/357026
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author Macko, Tibor
Brüll, Robert
Brinkmann, Christoph
Pasch, Harald
author_facet Macko, Tibor
Brüll, Robert
Brinkmann, Christoph
Pasch, Harald
author_sort Macko, Tibor
collection PubMed
description The automated procedure for the monitoring of the adsorption process in the solute-sorbent-solvent system has been elaborated. It uses commercially available instrument CRYSTAF model 200. The application of CRYSTAF enabled monitoring of adsorption of linear polyethylene with weight average molar masses of 2, 14, and 53 kg/mol from 1,2,4-trichlorobenzene onto zeolite SH-300 at temperature as high as 140°C. It is the authors' understanding that this is the first demonstration of an adsorption isotherms for polyethylene. The measurement with the CRYSTAF instrument reduces manual manipulations with dangerous solvents at high temperature and enables automated long-time monitoring of the concentration of the solute in an adsorption system.
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spelling pubmed-27305612009-08-25 Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C Macko, Tibor Brüll, Robert Brinkmann, Christoph Pasch, Harald J Autom Methods Manag Chem Research Article The automated procedure for the monitoring of the adsorption process in the solute-sorbent-solvent system has been elaborated. It uses commercially available instrument CRYSTAF model 200. The application of CRYSTAF enabled monitoring of adsorption of linear polyethylene with weight average molar masses of 2, 14, and 53 kg/mol from 1,2,4-trichlorobenzene onto zeolite SH-300 at temperature as high as 140°C. It is the authors' understanding that this is the first demonstration of an adsorption isotherms for polyethylene. The measurement with the CRYSTAF instrument reduces manual manipulations with dangerous solvents at high temperature and enables automated long-time monitoring of the concentration of the solute in an adsorption system. Hindawi Publishing Corporation 2009 2009-08-23 /pmc/articles/PMC2730561/ /pubmed/19707534 http://dx.doi.org/10.1155/2009/357026 Text en Copyright © 2009 Tibor Macko et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Macko, Tibor
Brüll, Robert
Brinkmann, Christoph
Pasch, Harald
Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title_full Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title_fullStr Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title_full_unstemmed Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title_short Automated Monitoring of the Establishment of the Adsorption Equilibrium: Adsorption of Polyethylene from 1,2,4-Trichlorobenzene onto a Zeolite at Temperature 140°C
title_sort automated monitoring of the establishment of the adsorption equilibrium: adsorption of polyethylene from 1,2,4-trichlorobenzene onto a zeolite at temperature 140°c
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2730561/
https://www.ncbi.nlm.nih.gov/pubmed/19707534
http://dx.doi.org/10.1155/2009/357026
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AT paschharald automatedmonitoringoftheestablishmentoftheadsorptionequilibriumadsorptionofpolyethylenefrom124trichlorobenzeneontoazeoliteattemperature140c

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