Radical carbonylations using a continuous microflow system

Radical-based carbonylation reactions of alkyl halides were conducted in a microflow reactor under pressurized carbon monoxide gas. Good to excellent yields of carbonylated products were obtained via radical formylation, carbonylative cyclization and three-component coupling reactions, using tributy...

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Detalles Bibliográficos
Autores principales: Fukuyama, Takahide, Rahman, Md Taifur, Kamata, Naoya, Ryu, Ilhyong
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Preliminary Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748689/
https://www.ncbi.nlm.nih.gov/pubmed/19777132
http://dx.doi.org/10.3762/bjoc.5.34
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author Fukuyama, Takahide
Rahman, Md Taifur
Kamata, Naoya
Ryu, Ilhyong
author_facet Fukuyama, Takahide
Rahman, Md Taifur
Kamata, Naoya
Ryu, Ilhyong
author_sort Fukuyama, Takahide
collection PubMed
description Radical-based carbonylation reactions of alkyl halides were conducted in a microflow reactor under pressurized carbon monoxide gas. Good to excellent yields of carbonylated products were obtained via radical formylation, carbonylative cyclization and three-component coupling reactions, using tributyltin hydride or TTMSS as a radical mediator.
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spelling pubmed-27486892009-09-23 Radical carbonylations using a continuous microflow system Fukuyama, Takahide Rahman, Md Taifur Kamata, Naoya Ryu, Ilhyong Beilstein J Org Chem Preliminary Communication Radical-based carbonylation reactions of alkyl halides were conducted in a microflow reactor under pressurized carbon monoxide gas. Good to excellent yields of carbonylated products were obtained via radical formylation, carbonylative cyclization and three-component coupling reactions, using tributyltin hydride or TTMSS as a radical mediator. Beilstein-Institut 2009-07-13 /pmc/articles/PMC2748689/ /pubmed/19777132 http://dx.doi.org/10.3762/bjoc.5.34 Text en Copyright © 2009, Fukuyama et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Preliminary Communication
Fukuyama, Takahide
Rahman, Md Taifur
Kamata, Naoya
Ryu, Ilhyong
Radical carbonylations using a continuous microflow system
title Radical carbonylations using a continuous microflow system
title_full Radical carbonylations using a continuous microflow system
title_fullStr Radical carbonylations using a continuous microflow system
title_full_unstemmed Radical carbonylations using a continuous microflow system
title_short Radical carbonylations using a continuous microflow system
title_sort radical carbonylations using a continuous microflow system
topic Preliminary Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748689/
https://www.ncbi.nlm.nih.gov/pubmed/19777132
http://dx.doi.org/10.3762/bjoc.5.34
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AT rahmanmdtaifur radicalcarbonylationsusingacontinuousmicroflowsystem
AT kamatanaoya radicalcarbonylationsusingacontinuousmicroflowsystem
AT ryuilhyong radicalcarbonylationsusingacontinuousmicroflowsystem

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