Synthesis and Diels–Alder cycloaddition reaction of norbornadiene and benzonorbornadiene dimers

Dimeric forms of norbornadiene and benzonorbornadiene were synthesized starting with known monobromide derivatives. The Diels–Alder cycloaddition reaction of dimers with TCNE and PTAD was investigated and new norbornenoid polycyclics were obtained. All compounds were characterized properly using NMR...

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Detalles Bibliográficos
Autores principales: Nişancı, Bilal, Dalkılıç, Erdin, Güney, Murat, Daştan, Arif
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2009
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748719/
https://www.ncbi.nlm.nih.gov/pubmed/19777139
http://dx.doi.org/10.3762/bjoc.5.39
Descripción
Sumario:Dimeric forms of norbornadiene and benzonorbornadiene were synthesized starting with known monobromide derivatives. The Diels–Alder cycloaddition reaction of dimers with TCNE and PTAD was investigated and new norbornenoid polycyclics were obtained. All compounds were characterized properly using NMR spectroscopy.

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