Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents

[Image: see text] Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Amin...

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Autores principales: Beaulieu, Francis, Beauregard, Louis-Philippe, Courchesne, Gabriel, Couturier, Michel, LaFlamme, François, L’Heureux, Alexandre
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2009
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2770860/
https://www.ncbi.nlm.nih.gov/pubmed/19799406
http://dx.doi.org/10.1021/ol902039q
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author Beaulieu, Francis
Beauregard, Louis-Philippe
Courchesne, Gabriel
Couturier, Michel
LaFlamme, François
L’Heureux, Alexandre
author_facet Beaulieu, Francis
Beauregard, Louis-Philippe
Courchesne, Gabriel
Couturier, Michel
LaFlamme, François
L’Heureux, Alexandre
author_sort Beaulieu, Francis
collection PubMed
description [Image: see text] Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Aminodifluorosulfinium tetrafluoroborates are easy handled crystalline salts that show enhanced thermal stability over dialkylaminosulfur trifluorides, are storage-stable, and unlike DAST and Deoxo-Fluor do not react violently with water.
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spelling pubmed-27708602009-11-02 Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents Beaulieu, Francis Beauregard, Louis-Philippe Courchesne, Gabriel Couturier, Michel LaFlamme, François L’Heureux, Alexandre Org Lett [Image: see text] Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Aminodifluorosulfinium tetrafluoroborates are easy handled crystalline salts that show enhanced thermal stability over dialkylaminosulfur trifluorides, are storage-stable, and unlike DAST and Deoxo-Fluor do not react violently with water. American Chemical Society 2009-10-02 2009-11-05 /pmc/articles/PMC2770860/ /pubmed/19799406 http://dx.doi.org/10.1021/ol902039q Text en Copyright © 2009 American Chemical Society http://pubs.acs.org This is an open-access article distributed under the ACS AuthorChoice Terms & Conditions. Any use of this article, must conform to the terms of that license which are available at http://pubs.acs.org.
spellingShingle Beaulieu, Francis
Beauregard, Louis-Philippe
Courchesne, Gabriel
Couturier, Michel
LaFlamme, François
L’Heureux, Alexandre
Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title_full Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title_fullStr Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title_full_unstemmed Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title_short Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
title_sort aminodifluorosulfinium tetrafluoroborate salts as stable and crystalline deoxofluorinating reagents
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2770860/
https://www.ncbi.nlm.nih.gov/pubmed/19799406
http://dx.doi.org/10.1021/ol902039q
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