Polyborylated reagents for modern organic synthesis

Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon–carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and ma...

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Detalles Bibliográficos
Autores principales: SHIMIZU, Masaki, HIYAMA, Tamejiro
Formato: Texto
Lenguaje:English
Publicado: The Japan Academy 2008
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2805506/
https://www.ncbi.nlm.nih.gov/pubmed/18941288
http://dx.doi.org/10.2183/pjab.84.75
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author SHIMIZU, Masaki
HIYAMA, Tamejiro
author_facet SHIMIZU, Masaki
HIYAMA, Tamejiro
author_sort SHIMIZU, Masaki
collection PubMed
description Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon–carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparative methods and synthetic reactions of di- and polyborylated reagents with the emphasis on multiple bond formation.
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spelling pubmed-28055062012-06-19 Polyborylated reagents for modern organic synthesis SHIMIZU, Masaki HIYAMA, Tamejiro Proc Jpn Acad Ser B Phys Biol Sci Review Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon–carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparative methods and synthetic reactions of di- and polyborylated reagents with the emphasis on multiple bond formation. The Japan Academy 2008-03 2008-03-12 /pmc/articles/PMC2805506/ /pubmed/18941288 http://dx.doi.org/10.2183/pjab.84.75 Text en © 2008 The Japan Academy This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Review
SHIMIZU, Masaki
HIYAMA, Tamejiro
Polyborylated reagents for modern organic synthesis
title Polyborylated reagents for modern organic synthesis
title_full Polyborylated reagents for modern organic synthesis
title_fullStr Polyborylated reagents for modern organic synthesis
title_full_unstemmed Polyborylated reagents for modern organic synthesis
title_short Polyborylated reagents for modern organic synthesis
title_sort polyborylated reagents for modern organic synthesis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2805506/
https://www.ncbi.nlm.nih.gov/pubmed/18941288
http://dx.doi.org/10.2183/pjab.84.75
work_keys_str_mv AT shimizumasaki polyborylatedreagentsformodernorganicsynthesis
AT hiyamatamejiro polyborylatedreagentsformodernorganicsynthesis

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