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Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency
Attempts have been made to develop dye-sensitized solar cells based on the principles and materials of photosynthesis: We first tested photosynthetic pigments, carotenoids (Cars), chlorophylls (Chls) and their derivatives, to find sensitizers showing reasonable performance (photocurrent and conversi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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Molecular Diversity Preservation International (MDPI)
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2808002/ https://www.ncbi.nlm.nih.gov/pubmed/20087456 http://dx.doi.org/10.3390/ijms10114575 |
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author | Koyama, Yasushi Miki, Takeshi Wang, Xiao-Feng Nagae, Hiroyoshi |
author_facet | Koyama, Yasushi Miki, Takeshi Wang, Xiao-Feng Nagae, Hiroyoshi |
author_sort | Koyama, Yasushi |
collection | PubMed |
description | Attempts have been made to develop dye-sensitized solar cells based on the principles and materials of photosynthesis: We first tested photosynthetic pigments, carotenoids (Cars), chlorophylls (Chls) and their derivatives, to find sensitizers showing reasonable performance (photocurrent and conversion efficiency). We then tried to introduce the principles of photosynthesis, including electron transfer and energy transfer from Car to Phe a. Also, we tried co-sensitization using the pheophorbide (Phe) a and Chl c(2) pair which further enhanced the performance of the component sensitizers as follows: J(sc) = 9.0 + 13.8 → 14.0 mA cm(−2) and η = 3.4 + 4.6 → 5.4%. |
format | Text |
id | pubmed-2808002 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | Molecular Diversity Preservation International (MDPI) |
record_format | MEDLINE/PubMed |
spelling | pubmed-28080022010-01-19 Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency Koyama, Yasushi Miki, Takeshi Wang, Xiao-Feng Nagae, Hiroyoshi Int J Mol Sci Review Attempts have been made to develop dye-sensitized solar cells based on the principles and materials of photosynthesis: We first tested photosynthetic pigments, carotenoids (Cars), chlorophylls (Chls) and their derivatives, to find sensitizers showing reasonable performance (photocurrent and conversion efficiency). We then tried to introduce the principles of photosynthesis, including electron transfer and energy transfer from Car to Phe a. Also, we tried co-sensitization using the pheophorbide (Phe) a and Chl c(2) pair which further enhanced the performance of the component sensitizers as follows: J(sc) = 9.0 + 13.8 → 14.0 mA cm(−2) and η = 3.4 + 4.6 → 5.4%. Molecular Diversity Preservation International (MDPI) 2009-11 2009-10-27 /pmc/articles/PMC2808002/ /pubmed/20087456 http://dx.doi.org/10.3390/ijms10114575 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0 This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Review Koyama, Yasushi Miki, Takeshi Wang, Xiao-Feng Nagae, Hiroyoshi Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title | Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title_full | Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title_fullStr | Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title_full_unstemmed | Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title_short | Dye-Sensitized Solar Cells Based on the Principles and Materials of Photosynthesis: Mechanisms of Suppression and Enhancement of Photocurrent and Conversion Efficiency |
title_sort | dye-sensitized solar cells based on the principles and materials of photosynthesis: mechanisms of suppression and enhancement of photocurrent and conversion efficiency |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2808002/ https://www.ncbi.nlm.nih.gov/pubmed/20087456 http://dx.doi.org/10.3390/ijms10114575 |
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