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Probing intermediates in the activation cycle of [NiFe] hydrogenase by infrared spectroscopy: the Ni-SI(r) state and its light sensitivity

The [NiFe] hydrogenase from the sulphate-reducing bacterium Desulfovibrio vulgaris Miyazaki F is reversibly inhibited in the presence of molecular oxygen. A key intermediate in the reactivation process, Ni-SI(r), provides the link between fully oxidized (Ni-A, Ni-B) and active (Ni-SI(a), Ni-C and Ni...

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Detalles Bibliográficos
Autores principales:	Pandelia, Maria-Eirini, Ogata, Hideaki, Currell, Leslie J., Flores, Marco, Lubitz, Wolfgang
Formato:	Texto
Lenguaje:	English
Publicado:	Springer-Verlag 2009
Materias:	Original Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2847147/ https://www.ncbi.nlm.nih.gov/pubmed/19626348 http://dx.doi.org/10.1007/s00775-009-0566-9

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