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From designer Lewis acid to designer Brønsted acid towards more reactive and selective acid catalysis
This review focuses on the development of acid catalysis for selective organic transformations conducted in our laboratories for the past 30 years. Several important concepts in designing of catalysts are described with some examples. Further, recent developments in super Brønsted acid and their app...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
The Japan Academy
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2858369/ https://www.ncbi.nlm.nih.gov/pubmed/18941293 http://dx.doi.org/10.2183/pjab.84.134 |
Sumario: | This review focuses on the development of acid catalysis for selective organic transformations conducted in our laboratories for the past 30 years. Several important concepts in designing of catalysts are described with some examples. Further, recent developments in super Brønsted acid and their applications in a one-pot procedure to construct complex molecules with high diastereoselectivities are described. |
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