Studies on Polyethers Produced by Red Algae

Two novel squalene-derived triterpenes, spirodehydrovenustatriol (3) and 14-keto-dehydrothyrsiferol (4) were isolated from the red alga Laurencia viridis, together with two new and unusual C(17) terpenoids, adejen A (5) and B (6). These truncated structures possess structural similarities with other...

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Detalles Bibliográficos
Autores principales: Cen-Pacheco, Francisco, Nordström, Laurette, Souto, María Luisa, Martín, Manuel Norte, Fernández, José Javier, Daranas, Antonio Hernández
Formato: Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2866481/
https://www.ncbi.nlm.nih.gov/pubmed/20479973
http://dx.doi.org/10.3390/md8041178
Descripción
Sumario:Two novel squalene-derived triterpenes, spirodehydrovenustatriol (3) and 14-keto-dehydrothyrsiferol (4) were isolated from the red alga Laurencia viridis, together with two new and unusual C(17) terpenoids, adejen A (5) and B (6). These truncated structures possess structural similarities with other known squalene metabolites and their biogenetic origin has been proposed on the basis of an oxidative process of the squalene skeleton. All the structures were elucidated by extensive use of 2D NMR spectroscopic methods.

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