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Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles

The Prins reaction was investigated using BF(3)·OEt(2) as a Lewis acid. It has been recently demonstrated, that if BF(3)·OEt(2) is used in stoichiometric amounts then these reactions generate fluorinated products where the BF(3)·OEt(2) contributes fluoride ion to quench the intermediate carbocations...

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Detalles Bibliográficos
Autores principales:	Launay, Guillaume G, Slawin, Alexandra M Z, O'Hagan, David
Formato:	Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2010
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2874316/ https://www.ncbi.nlm.nih.gov/pubmed/20502655 http://dx.doi.org/10.3762/bjoc.6.41

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