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Use of Empirical Correlations to Determine Solvent Effects in the Solvolysis of S-Methyl Chlorothioformate

The specific rates of solvolysis of S-methyl chlorothioformate (MeSCOCl) are analyzed in 20 solvents of widely varying nucleophilicity and ionizing power at 25.0 °C using the extended Grunwald-Winstein Equation. A stepwise S(N)1 (D(N) + A(N)) mechanism is proposed in the more ionizing solvents inclu...

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Detalles Bibliográficos
Autores principales:	D’Souza, Malcolm J., Hailey, Stefan M., Kevill, Dennis N.
Formato:	Texto
Lenguaje:	English
Publicado:	Molecular Diversity Preservation International (MDPI) 2010
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2885106/ https://www.ncbi.nlm.nih.gov/pubmed/20559514 http://dx.doi.org/10.3390/ijms11052253

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