Autohydration of Nanosized Cubic Zirconium Tungstate

[Image: see text] Nanoparticulate zirconium tungstate prepared through hydrothermal methods was found to autohydrate under ambient conditions. This results in positive thermal expansion, limiting its usefulness for controlled thermal expansion composites. TEM and BET studies provided strong evidence...

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Autores principales: Banek, Nathan A., Baiz, Hassan I., Latigo, Akena, Lind, Cora
Formato: Texto
Lenguaje:English
Publicado: American Chemical Society 2010
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2886602/
https://www.ncbi.nlm.nih.gov/pubmed/20521830
http://dx.doi.org/10.1021/ja101475f
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author Banek, Nathan A.
Baiz, Hassan I.
Latigo, Akena
Lind, Cora
author_facet Banek, Nathan A.
Baiz, Hassan I.
Latigo, Akena
Lind, Cora
author_sort Banek, Nathan A.
collection PubMed
description [Image: see text] Nanoparticulate zirconium tungstate prepared through hydrothermal methods was found to autohydrate under ambient conditions. This results in positive thermal expansion, limiting its usefulness for controlled thermal expansion composites. TEM and BET studies provided strong evidence that the cause of autohydration is a result of structural defects present in the nanoparticles, while kinetics are governed by surface area, suggesting that processing methods can be used to minimize or overcome this problem.
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spelling pubmed-28866022010-06-16 Autohydration of Nanosized Cubic Zirconium Tungstate Banek, Nathan A. Baiz, Hassan I. Latigo, Akena Lind, Cora J Am Chem Soc [Image: see text] Nanoparticulate zirconium tungstate prepared through hydrothermal methods was found to autohydrate under ambient conditions. This results in positive thermal expansion, limiting its usefulness for controlled thermal expansion composites. TEM and BET studies provided strong evidence that the cause of autohydration is a result of structural defects present in the nanoparticles, while kinetics are governed by surface area, suggesting that processing methods can be used to minimize or overcome this problem. American Chemical Society 2010-06-03 2010-06-23 /pmc/articles/PMC2886602/ /pubmed/20521830 http://dx.doi.org/10.1021/ja101475f Text en Copyright © 2010 American Chemical Society http://pubs.acs.org This is an open-access article distributed under the ACS AuthorChoice Terms & Conditions. Any use of this article, must conform to the terms of that license which are available at http://pubs.acs.org.
spellingShingle Banek, Nathan A.
Baiz, Hassan I.
Latigo, Akena
Lind, Cora
Autohydration of Nanosized Cubic Zirconium Tungstate
title Autohydration of Nanosized Cubic Zirconium Tungstate
title_full Autohydration of Nanosized Cubic Zirconium Tungstate
title_fullStr Autohydration of Nanosized Cubic Zirconium Tungstate
title_full_unstemmed Autohydration of Nanosized Cubic Zirconium Tungstate
title_short Autohydration of Nanosized Cubic Zirconium Tungstate
title_sort autohydration of nanosized cubic zirconium tungstate
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2886602/
https://www.ncbi.nlm.nih.gov/pubmed/20521830
http://dx.doi.org/10.1021/ja101475f
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AT latigoakena autohydrationofnanosizedcubiczirconiumtungstate
AT lindcora autohydrationofnanosizedcubiczirconiumtungstate

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