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9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine

Reaction of tetrafluoropyridazine with catechol gives a tricyclic 9,10-dioxa-1,2-diaza-anthracene system by a sequential nucleophilic aromatic substitution ring annelation process, further extending the use of perfluoroheteroaromatic derivatives for the synthesis of unusual polyfunctional heterocycl...

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Detalles Bibliográficos
Autores principales: Pattison, Graham, Sandford, Graham, Yufit, Dmitrii S, Howard, Judith A K, Christopher, John A, Miller, David D
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2887278/
https://www.ncbi.nlm.nih.gov/pubmed/20563272
http://dx.doi.org/10.3762/bjoc.6.45
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author Pattison, Graham
Sandford, Graham
Yufit, Dmitrii S
Howard, Judith A K
Christopher, John A
Miller, David D
author_facet Pattison, Graham
Sandford, Graham
Yufit, Dmitrii S
Howard, Judith A K
Christopher, John A
Miller, David D
author_sort Pattison, Graham
collection PubMed
description Reaction of tetrafluoropyridazine with catechol gives a tricyclic 9,10-dioxa-1,2-diaza-anthracene system by a sequential nucleophilic aromatic substitution ring annelation process, further extending the use of perfluoroheteroaromatic derivatives for the synthesis of unusual polyfunctional heterocyclic architectures. The tricyclic scaffold reacts with amines and sodium ethoxide providing a short series of functional 9,10-dioxa-1,2-diaza-anthracene systems.
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spelling pubmed-28872782010-06-18 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine Pattison, Graham Sandford, Graham Yufit, Dmitrii S Howard, Judith A K Christopher, John A Miller, David D Beilstein J Org Chem Full Research Paper Reaction of tetrafluoropyridazine with catechol gives a tricyclic 9,10-dioxa-1,2-diaza-anthracene system by a sequential nucleophilic aromatic substitution ring annelation process, further extending the use of perfluoroheteroaromatic derivatives for the synthesis of unusual polyfunctional heterocyclic architectures. The tricyclic scaffold reacts with amines and sodium ethoxide providing a short series of functional 9,10-dioxa-1,2-diaza-anthracene systems. Beilstein-Institut 2010-05-06 /pmc/articles/PMC2887278/ /pubmed/20563272 http://dx.doi.org/10.3762/bjoc.6.45 Text en Copyright © 2010, Pattison et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Pattison, Graham
Sandford, Graham
Yufit, Dmitrii S
Howard, Judith A K
Christopher, John A
Miller, David D
9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title_full 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title_fullStr 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title_full_unstemmed 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title_short 9,10-Dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
title_sort 9,10-dioxa-1,2-diaza-anthracene derivatives from tetrafluoropyridazine
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2887278/
https://www.ncbi.nlm.nih.gov/pubmed/20563272
http://dx.doi.org/10.3762/bjoc.6.45
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