Cargando…
Triggering N(2) Uptake via Redox Induced Expulsion of Coordinated NH(3) and N(2) Silylation at Trigonal Bipyramidal Iron
The biological reduction of nitrogen to ammonia may occur via one of two predominant pathways in which nitrogenous N(x)H(y) intermediates including hydrazine (N(2)H(4)), diazene (N(2)H(2)), nitride (N(3-)) and imide (NH(2-)) may be involved. To test the validity of hypotheses concerning iron’s direc...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2892393/ https://www.ncbi.nlm.nih.gov/pubmed/20571574 http://dx.doi.org/10.1038/nchem.660 |