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Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization
Thermosensitive nanocables consisting of Au nanowire cores and poly(N-isopropylacrylamide) sheaths (denoted as Au/PNIPAAm) were synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP). The formation of PNIPAAm sheath was verified by Fourier transform infrared (FTIR) and hydro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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Springer
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893766/ https://www.ncbi.nlm.nih.gov/pubmed/20592960 http://dx.doi.org/10.1007/s11671-008-9206-5 |
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author | Wei, Qingshan Zhou, Wenbo Ji, Jian Shen, Jiacong |
author_facet | Wei, Qingshan Zhou, Wenbo Ji, Jian Shen, Jiacong |
author_sort | Wei, Qingshan |
collection | PubMed |
description | Thermosensitive nanocables consisting of Au nanowire cores and poly(N-isopropylacrylamide) sheaths (denoted as Au/PNIPAAm) were synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP). The formation of PNIPAAm sheath was verified by Fourier transform infrared (FTIR) and hydrogen nuclear magnetic resonance ((1)H NMR) spectroscopy. Transmission electron microscope (TEM) results confirmed the core/shell structure of nanohybrids. The thickness and density of PNIPAAm sheaths can be adjusted by controlling the amount of cross-linker during the polymerization. Signature temperature response was observed from Au/cross-linked-PNIPAAm nanocables. Such smart nanocables show immense potentials as building blocks for novel thermosensitive nanodevices in future. |
format | Text |
id | pubmed-2893766 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | Springer |
record_format | MEDLINE/PubMed |
spelling | pubmed-28937662010-06-29 Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization Wei, Qingshan Zhou, Wenbo Ji, Jian Shen, Jiacong Nanoscale Res Lett Nano Express Thermosensitive nanocables consisting of Au nanowire cores and poly(N-isopropylacrylamide) sheaths (denoted as Au/PNIPAAm) were synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP). The formation of PNIPAAm sheath was verified by Fourier transform infrared (FTIR) and hydrogen nuclear magnetic resonance ((1)H NMR) spectroscopy. Transmission electron microscope (TEM) results confirmed the core/shell structure of nanohybrids. The thickness and density of PNIPAAm sheaths can be adjusted by controlling the amount of cross-linker during the polymerization. Signature temperature response was observed from Au/cross-linked-PNIPAAm nanocables. Such smart nanocables show immense potentials as building blocks for novel thermosensitive nanodevices in future. Springer 2008-11-19 /pmc/articles/PMC2893766/ /pubmed/20592960 http://dx.doi.org/10.1007/s11671-008-9206-5 Text en Copyright ©2008 to the authors |
spellingShingle | Nano Express Wei, Qingshan Zhou, Wenbo Ji, Jian Shen, Jiacong Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title | Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title_full | Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title_fullStr | Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title_full_unstemmed | Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title_short | Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization |
title_sort | thermosensitive nanocables prepared by surface-initiated atom transfer radical polymerization |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2893766/ https://www.ncbi.nlm.nih.gov/pubmed/20592960 http://dx.doi.org/10.1007/s11671-008-9206-5 |
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