Magnesium Ferrite (MgFe(2)O(4)) Nanostructures Fabricated by Electrospinning

Magnesium ferrite (MgFe(2)O(4)) nanostructures were successfully fabricated by electrospinning method. X-ray diffraction, FT-IR, scanning electron microscopy, and transmission electron microscopy revealed that calcination of the as-spun MgFe(2)O(4)/poly(vinyl pyrrolidone) (PVP) composite nanofibers at 500–800 °C in air for 2 h resulted in well-developed spinel MgFe(2)O(4)nanostuctures. The crystal structure and morphology of the nanofibers were influenced by the calcination temperature. Crystallite size of the nanoparticles contained in nanofibers increased from 15 ± 4 to 24 ± 3 nm when calcination temperature was increased from 500 to 800 °C. Room temperature magnetization results showed a ferromagnetic behavior of the calcined MgFe(2)O(4)/PVP composite nanofibers, having their specific saturation magnetization (M(s)) values of 17.0, 20.7, 25.7, and 31.1 emu/g at 10 Oe for the samples calcined at 500, 600, 700, and 800 °C, respectively. It is found that the increase in the tendency ofM(s)is consistent with the enhancement of crystallinity, and the values ofM(s)for the MgFe(2)O(4)samples were observed to increase with increasing crystallite size.