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Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898652/ https://www.ncbi.nlm.nih.gov/pubmed/19597604 http://dx.doi.org/10.1039/b908754k |
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author | Kawasaki, Tsuneomi Shimizu, Masako Nishiyama, Daisuke Ito, Masateru Ozawa, Hitomi Soai, Kenso |
author_facet | Kawasaki, Tsuneomi Shimizu, Masako Nishiyama, Daisuke Ito, Masateru Ozawa, Hitomi Soai, Kenso |
author_sort | Kawasaki, Tsuneomi |
collection | PubMed |
description | Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols. |
format | Text |
id | pubmed-2898652 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-28986522011-09-26 Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality Kawasaki, Tsuneomi Shimizu, Masako Nishiyama, Daisuke Ito, Masateru Ozawa, Hitomi Soai, Kenso Chem Commun (Camb) Chemistry Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols. Royal Society of Chemistry 2009-08-07 2009-06-24 /pmc/articles/PMC2898652/ /pubmed/19597604 http://dx.doi.org/10.1039/b908754k Text en This journal is © The Royal Society of Chemistry 2009 http://creativecommons.org/licenses/by-nc/2.0/uk/ This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/2.0/uk/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Chemistry Kawasaki, Tsuneomi Shimizu, Masako Nishiyama, Daisuke Ito, Masateru Ozawa, Hitomi Soai, Kenso Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality |
title | Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
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title_full | Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
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title_fullStr | Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
|
title_full_unstemmed | Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
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title_short | Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
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title_sort | asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898652/ https://www.ncbi.nlm.nih.gov/pubmed/19597604 http://dx.doi.org/10.1039/b908754k |
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