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Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.

Detalles Bibliográficos
Autores principales: Kawasaki, Tsuneomi, Shimizu, Masako, Nishiyama, Daisuke, Ito, Masateru, Ozawa, Hitomi, Soai, Kenso
Formato: Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898652/
https://www.ncbi.nlm.nih.gov/pubmed/19597604
http://dx.doi.org/10.1039/b908754k
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author Kawasaki, Tsuneomi
Shimizu, Masako
Nishiyama, Daisuke
Ito, Masateru
Ozawa, Hitomi
Soai, Kenso
author_facet Kawasaki, Tsuneomi
Shimizu, Masako
Nishiyama, Daisuke
Ito, Masateru
Ozawa, Hitomi
Soai, Kenso
author_sort Kawasaki, Tsuneomi
collection PubMed
description Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.
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spelling pubmed-28986522011-09-26 Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality Kawasaki, Tsuneomi Shimizu, Masako Nishiyama, Daisuke Ito, Masateru Ozawa, Hitomi Soai, Kenso Chem Commun (Camb) Chemistry Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols. Royal Society of Chemistry 2009-08-07 2009-06-24 /pmc/articles/PMC2898652/ /pubmed/19597604 http://dx.doi.org/10.1039/b908754k Text en This journal is © The Royal Society of Chemistry 2009 http://creativecommons.org/licenses/by-nc/2.0/uk/ This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/2.0/uk/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Kawasaki, Tsuneomi
Shimizu, Masako
Nishiyama, Daisuke
Ito, Masateru
Ozawa, Hitomi
Soai, Kenso
Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title_full Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title_fullStr Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title_full_unstemmed Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title_short Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
title_sort asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2898652/
https://www.ncbi.nlm.nih.gov/pubmed/19597604
http://dx.doi.org/10.1039/b908754k
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