Anthracene functionalized terpyridines – synthesis and properties

The synthesis of several symmetrically 4,4″-functionalized 2,2′:6′,2″-terpyridines is reported. In addition to the biscarboxylic acid 4,4″-tpy(CO(2)H)(2) (3), the anthryl esters 4,4″-tpy(CO(2)CH(2)Anth)(2) (5a) and 4,4″-tpy(CO(2)CH(2)CH(2)OAnth)(2) (5b) were synthesized. Furthermore, both anthryl es...

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Detalles Bibliográficos
Autores principales: Wehmeier, Falk, Mattay, Jochen
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2900913/
https://www.ncbi.nlm.nih.gov/pubmed/20625526
http://dx.doi.org/10.3762/bjoc.6.54
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author Wehmeier, Falk
Mattay, Jochen
author_facet Wehmeier, Falk
Mattay, Jochen
author_sort Wehmeier, Falk
collection PubMed
description The synthesis of several symmetrically 4,4″-functionalized 2,2′:6′,2″-terpyridines is reported. In addition to the biscarboxylic acid 4,4″-tpy(CO(2)H)(2) (3), the anthryl esters 4,4″-tpy(CO(2)CH(2)Anth)(2) (5a) and 4,4″-tpy(CO(2)CH(2)CH(2)OAnth)(2) (5b) were synthesized. Furthermore, both anthryl esters were used to synthesize symmetric iron(II)-bis(terpyridine)complexes 6a–b. Irradiation experiments were carried out with both the free ligands and an iron(II)-complex in order to investigate the photochemistry of the compounds.
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spelling pubmed-29009132010-07-12 Anthracene functionalized terpyridines – synthesis and properties Wehmeier, Falk Mattay, Jochen Beilstein J Org Chem Full Research Paper The synthesis of several symmetrically 4,4″-functionalized 2,2′:6′,2″-terpyridines is reported. In addition to the biscarboxylic acid 4,4″-tpy(CO(2)H)(2) (3), the anthryl esters 4,4″-tpy(CO(2)CH(2)Anth)(2) (5a) and 4,4″-tpy(CO(2)CH(2)CH(2)OAnth)(2) (5b) were synthesized. Furthermore, both anthryl esters were used to synthesize symmetric iron(II)-bis(terpyridine)complexes 6a–b. Irradiation experiments were carried out with both the free ligands and an iron(II)-complex in order to investigate the photochemistry of the compounds. Beilstein-Institut 2010-05-27 /pmc/articles/PMC2900913/ /pubmed/20625526 http://dx.doi.org/10.3762/bjoc.6.54 Text en Copyright © 2010, Wehmeier and Mattay https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Wehmeier, Falk
Mattay, Jochen
Anthracene functionalized terpyridines – synthesis and properties
title Anthracene functionalized terpyridines – synthesis and properties
title_full Anthracene functionalized terpyridines – synthesis and properties
title_fullStr Anthracene functionalized terpyridines – synthesis and properties
title_full_unstemmed Anthracene functionalized terpyridines – synthesis and properties
title_short Anthracene functionalized terpyridines – synthesis and properties
title_sort anthracene functionalized terpyridines – synthesis and properties
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2900913/
https://www.ncbi.nlm.nih.gov/pubmed/20625526
http://dx.doi.org/10.3762/bjoc.6.54
work_keys_str_mv AT wehmeierfalk anthracenefunctionalizedterpyridinessynthesisandproperties
AT mattayjochen anthracenefunctionalizedterpyridinessynthesisandproperties

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