A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions

The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand’s photochromism and investigations regarding the influence of various transition metal ions on the photochromic reaction are presented. The photochromism of t...

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Autores principales: Wehmeier, Falk, Mattay, Jochen
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2900936/
https://www.ncbi.nlm.nih.gov/pubmed/20625529
http://dx.doi.org/10.3762/bjoc.6.53
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author Wehmeier, Falk
Mattay, Jochen
author_facet Wehmeier, Falk
Mattay, Jochen
author_sort Wehmeier, Falk
collection PubMed
description The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand’s photochromism and investigations regarding the influence of various transition metal ions on the photochromic reaction are presented. The photochromism of the central diarylethene unit is strongly dependent on the transition metal present, vice versa the photochromic reaction seems to influence the MLCT transition of a binuclear Ru(II) complex.
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spelling pubmed-29009362010-07-12 A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions Wehmeier, Falk Mattay, Jochen Beilstein J Org Chem Full Research Paper The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand’s photochromism and investigations regarding the influence of various transition metal ions on the photochromic reaction are presented. The photochromism of the central diarylethene unit is strongly dependent on the transition metal present, vice versa the photochromic reaction seems to influence the MLCT transition of a binuclear Ru(II) complex. Beilstein-Institut 2010-05-26 /pmc/articles/PMC2900936/ /pubmed/20625529 http://dx.doi.org/10.3762/bjoc.6.53 Text en Copyright © 2010, Wehmeier and Mattay https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Wehmeier, Falk
Mattay, Jochen
A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title_full A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title_fullStr A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title_full_unstemmed A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title_short A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
title_sort perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2900936/
https://www.ncbi.nlm.nih.gov/pubmed/20625529
http://dx.doi.org/10.3762/bjoc.6.53
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