“Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)

The synthesis, NMR characterization, and X-ray crystallography of “lantern-shaped” platinum(III) complexes with four pivaloamidate bridging ligands and two 9-ethylguanines (9-EtG) or 1-methylcytosines (1-MeC) in axial positions are reported: cis-N(2)O(2)-[Pt(2){HN=C(Bu(t))O}(4)(9-EtG)(2)](NO(3))(2)...

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Detalles Bibliográficos
Autores principales: Pacifico, Concetta, Intini, Francesco Paolo, Nushi, Fiorentin, Natile, Giovanni
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2010
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901605/
https://www.ncbi.nlm.nih.gov/pubmed/20631827
http://dx.doi.org/10.1155/2010/102863
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author Pacifico, Concetta
Intini, Francesco Paolo
Nushi, Fiorentin
Natile, Giovanni
author_facet Pacifico, Concetta
Intini, Francesco Paolo
Nushi, Fiorentin
Natile, Giovanni
author_sort Pacifico, Concetta
collection PubMed
description The synthesis, NMR characterization, and X-ray crystallography of “lantern-shaped” platinum(III) complexes with four pivaloamidate bridging ligands and two 9-ethylguanines (9-EtG) or 1-methylcytosines (1-MeC) in axial positions are reported: cis-N(2)O(2)-[Pt(2){HN=C(Bu(t))O}(4)(9-EtG)(2)](NO(3))(2) and cis-N(2)O(2)-[Pt(2){HN=C(Bu(t))O}(4)(1-MeC)(2)](NO(3))(2). The last complex is, to the best of our knowledge, the first dinuclear compound of platinum(III) with axially bound 1-MeC.
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spelling pubmed-29016052010-07-14 “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2) Pacifico, Concetta Intini, Francesco Paolo Nushi, Fiorentin Natile, Giovanni Bioinorg Chem Appl Research Article The synthesis, NMR characterization, and X-ray crystallography of “lantern-shaped” platinum(III) complexes with four pivaloamidate bridging ligands and two 9-ethylguanines (9-EtG) or 1-methylcytosines (1-MeC) in axial positions are reported: cis-N(2)O(2)-[Pt(2){HN=C(Bu(t))O}(4)(9-EtG)(2)](NO(3))(2) and cis-N(2)O(2)-[Pt(2){HN=C(Bu(t))O}(4)(1-MeC)(2)](NO(3))(2). The last complex is, to the best of our knowledge, the first dinuclear compound of platinum(III) with axially bound 1-MeC. Hindawi Publishing Corporation 2010 2010-06-08 /pmc/articles/PMC2901605/ /pubmed/20631827 http://dx.doi.org/10.1155/2010/102863 Text en Copyright © 2010 Concetta Pacifico et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Pacifico, Concetta
Intini, Francesco Paolo
Nushi, Fiorentin
Natile, Giovanni
“Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title_full “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title_fullStr “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title_full_unstemmed “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title_short “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt(2){HN=C(Bu(t))O}(4)L(2)](NO(3))(2)
title_sort “lantern-shaped” platinum(iii) complexes with axially bound 9-ethylguanine or 1-methylcytosine (l) of general formula [pt(2){hn=c(bu(t))o}(4)l(2)](no(3))(2)
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901605/
https://www.ncbi.nlm.nih.gov/pubmed/20631827
http://dx.doi.org/10.1155/2010/102863
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