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Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three...
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Formato: | Texto |
Lenguaje: | English |
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Hindawi Publishing Corporation
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901614/ https://www.ncbi.nlm.nih.gov/pubmed/20631832 http://dx.doi.org/10.1155/2010/104329 |
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author | Kostakis, George E. Anson, Christopher E. Powell, Annie K. |
author_facet | Kostakis, George E. Anson, Christopher E. Powell, Annie K. |
author_sort | Kostakis, George E. |
collection | PubMed |
description | The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network. |
format | Text |
id | pubmed-2901614 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | Hindawi Publishing Corporation |
record_format | MEDLINE/PubMed |
spelling | pubmed-29016142010-07-14 Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex Kostakis, George E. Anson, Christopher E. Powell, Annie K. Bioinorg Chem Appl Research Article The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network. Hindawi Publishing Corporation 2010 2010-06-15 /pmc/articles/PMC2901614/ /pubmed/20631832 http://dx.doi.org/10.1155/2010/104329 Text en Copyright © 2010 George E. Kostakis et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Kostakis, George E. Anson, Christopher E. Powell, Annie K. Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title | Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title_full | Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title_fullStr | Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title_full_unstemmed | Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title_short | Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex |
title_sort | synthesis and supramolecular structure of a (5-(3-(1h-tetrazol-5-yl)phenyl)-1h-tetrazole) cobalt complex |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901614/ https://www.ncbi.nlm.nih.gov/pubmed/20631832 http://dx.doi.org/10.1155/2010/104329 |
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