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Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex

The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three...

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Detalles Bibliográficos
Autores principales: Kostakis, George E., Anson, Christopher E., Powell, Annie K.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901614/
https://www.ncbi.nlm.nih.gov/pubmed/20631832
http://dx.doi.org/10.1155/2010/104329
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author Kostakis, George E.
Anson, Christopher E.
Powell, Annie K.
author_facet Kostakis, George E.
Anson, Christopher E.
Powell, Annie K.
author_sort Kostakis, George E.
collection PubMed
description The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network.
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spelling pubmed-29016142010-07-14 Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex Kostakis, George E. Anson, Christopher E. Powell, Annie K. Bioinorg Chem Appl Research Article The reaction of CoCl(2) ·6H(2)O with m-BDTH(2) (1,3-benzeneditetrazol-5-yl) leads to [Co(C(8)H(6)N(8))(2)(H(2)O)(2)(CH(3)CN)(2)]Cl(2) (1). Both tetrazolic groups remain protonated existing in a 1H tautomeric form. A trifurcated chlorine atom and stacking interactions assemble compound 1 into a three-dimensional network. Hindawi Publishing Corporation 2010 2010-06-15 /pmc/articles/PMC2901614/ /pubmed/20631832 http://dx.doi.org/10.1155/2010/104329 Text en Copyright © 2010 George E. Kostakis et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Kostakis, George E.
Anson, Christopher E.
Powell, Annie K.
Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_full Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_fullStr Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_full_unstemmed Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_short Synthesis and Supramolecular Structure of a (5-(3-(1H-tetrazol-5-yl)phenyl)-1H-tetrazole) Cobalt Complex
title_sort synthesis and supramolecular structure of a (5-(3-(1h-tetrazol-5-yl)phenyl)-1h-tetrazole) cobalt complex
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901614/
https://www.ncbi.nlm.nih.gov/pubmed/20631832
http://dx.doi.org/10.1155/2010/104329
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