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Molecular Architectures Derived from Metal Ions and the Flexible 3,3′-Bipyridine Ligand: Unexpected Dimer with Hg(II)

The flexible ditopic ligand 3,3′-bipyridine (3,3′-bpy) has been reacted with a series of transition metal species (Ag(+), Hg(2+), cis-a(2)M(2+) (a = NH(3) or a(2) = en; M = Pt, Pd), trans-a(2)Pt(2+) (a = NH(3))) in an attempt to produce discrete cyclic constructs. While Ag(+) gave a polymeric struct...

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Detalles Bibliográficos
Autores principales: Khutia, Anupam, Sanz Miguel, Pablo J., Lippert, Bernhard
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901620/
https://www.ncbi.nlm.nih.gov/pubmed/20631837
http://dx.doi.org/10.1155/2010/169054